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标准状况 (standard temperature and pressure, STP,常温常压),简称「标况」 由於地表各處的溫度、壓强皆不同,即使是同一地點的溫度壓强也隨測量時間不同而相異,因此為研究方便,制定出描述物質特徵的標準狀況:0 ℃(273.15 K)、100kPa,這樣的定義接近海平面上水的冰點。1莫耳的理想氣體在STP下占有的體積為22.413996(39) L(CODATA 2002),為標準莫耳體積 (standard molar volume)。這是区别一般条件而制定的标准。
历史上由巴黎制定的通行欧洲的舊制標準如下:
- 压强 p = 1 atm = 101325 帕斯卡 = 1013.25 hPa = 101.325 kPa = 1.01325 bar
- 温度 T = 298.15 K ≙ 25 °C ,空气密度 ρ = 1.184 kg/m³.
- 现在也使用T = 293.15 K ≙ 20 °C 空气密度 ρ = 1.204 kg/m³.
在化学和生物化学中另外还包括定义的观察反应物浓度,一般情况下为1mol/L (1 M)。在生物化学中只有质子例外(H+)。限定pH为7,即10-7 mol/l H+离子浓度用于准生理条件描述,肌体条件,细胞内部条件等。
注釋:
- EGIA:加拿大电力和燃气检验法
- SATP:标准的环境压力和温度
- SCAQMD:加州南海岸空气质量管理区
参看
參考資料
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- ^ ISO (1994), ISO 10780:1994 : Stationary source emissions - Measurement of velocity and volume flowrate of gas streams in ducts
- ^ 3.0 3.1 Robert C. Weast (Editor)(1975年).Handbook of Physics and Chemistry,56th Edition,CRC Press,F201–F206.ISBN 0-87819-455-X.
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- ^ "Design and Uncertainty for a PVTt Gas Flow Standard", Journal of Research of the National Institute of Standards and Technology, Vol.108, Number 1, 2003 NIST Journal
- ^ "National Primary and Secondary Ambient Air Quality Standards", 40 CFR--Protection of the Environment, Chapter I, Part 50, Section 50.3, 1998 National Ambient Air Standards
- ^ "Table of Chemical Thermodynamic Properties", National Bureau of Standards (NBS), Journal of Physics and Chemical Reference Data, 1982, Vol. 11, Supplement 2.
- ^ "Glossary", 2002, Compressed Air and Gas Institute, Cleveland, OH, USA Glossary
- ^ 12.0 12.1 The SI Metric System of Units and SPE Metric Standard 1984, Richardson, TX, USA (Notes for Table 2.3 on page 25 define standard cubic foot and standard cubic meter)
- ^ "Storage and Handling of Liquefied Petroleum Gases" and "Storage and Handling of Anhydrous Ammonia", 29 CFR--Labor, Chapter XVII--Occupational Safety and Health Administration, Part 1910, Sect. 1910.110 and 1910.111, 1993 Storage/Handling of LPG
- ^ "Rule 102, Definition of Terms (Standard Conditions)", Amended December 2004, South Coast Air Quality Management District, Los Angeles, California, USA SCAQMD Rule 102
- ^ "Annual Statistical Bulletin", 2004, Editor-in-chief: Dr. Omar Ibrahim, Organization of the Petroleum Exporting Countries, Vienna, Austria OPEC Statistical Bulletin
- ^ "Natural Gas Annual 2004", DOE/EIA-0131(04), December 2005, U.S. Department of Energy, Energy Information Administration, Washington, D.C., USA Natural Gas Annual 2004
- ^ Sierra Bullets L.P..“Chapter 3 – Effects of Altitude and Atmospheric Conditions”,Rifle and Handgun Reloading Manual, 5th Edition. "Effects of Altitude and Atmospheric Conditions", Exterior Ballistics Section, Sierra's "Rifle and Handgun Reloading Manual, 5th Edition", Sedalia, MO, USA Exterior Ballistics
- ^ The pressure is specified as 750 mmHg. However, the mmHg is temperature dependant, as mercury expands as temperature goes up. Here the values for the 0-20°C range are given.
- ^ "Gas turbines – Procurement – Part 2: Standard reference conditions and ratings", ISO 3977-2:1997 and "Gas turbines - Acceptance tests", ISO 2314:1989, Edition 2, International Organization for Standardization, Geneva, Switzerland ISO
- ^ ANSI/AMCA Standard 210, "Laboratory Methods Of Testing Fans for Aerodynamic Performance Rating", as implied here: http://www.greenheck.com/pdf/centrifugal/Plug.pdf when accessed on October 17, 2007
- ^ The standard is given as 29.92 inHg at an unspecified temperature. This most likely corresponds to a standard pressure of 101.325 kPa, converted into ~29.921 inHg at 32 °F)
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